An immobilized homogeneous catalyst for efficient and selective hydrogenation of functionalized aldehydes, alkenes, and alkynes

Authors
Burk, MJ Gerlach, A Semmeril, D
Citation
Mj. Burk et al., An immobilized homogeneous catalyst for efficient and selective hydrogenation of functionalized aldehydes, alkenes, and alkynes, J ORG CHEM, 65(26), 2000, pp. 8933-8939
Citations number
22
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANIC CHEMISTRY
ISSN journal
00223263 → ACNP
Volume
65
Issue
26
Year of publication
2000
Pages
8933 - 8939
Database
ISI
SICI code
0022-3263(200012)65:26<8933:AIHCFE>2.0.ZU;2-B
Abstract
An immobilized cationic rhodium(I) catalyst bearing the diphosphine 1,1'-bi s(diisopropylphosphino)ferrocene (DiPFc; 1) allows efficient and chemoselec tive hydrogenation of a range of functionalized aldehydes as well as alkene s and alkynes, under mild conditions. This heterogenized catalyst system is convenient to prepare, is stable to air and moisture over extended periods , and is readily recycled.