Total synthesis of Amaryllidaceae alkaloids utilizing sequential intramolecular heterocyclic azadiene Diels-Alder reactions of an unsymmetrical 1,2,4,5-tetrazine

Authors
Boger, DL Wolkenberg, SE
Citation
Dl. Boger et Se. Wolkenberg, Total synthesis of Amaryllidaceae alkaloids utilizing sequential intramolecular heterocyclic azadiene Diels-Alder reactions of an unsymmetrical 1,2,4,5-tetrazine, J ORG CHEM, 65(26), 2000, pp. 9120-9124
Citations number
40
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANIC CHEMISTRY
ISSN journal
00223263 → ACNP
Volume
65
Issue
26
Year of publication
2000
Pages
9120 - 9124
Database
ISI
SICI code
0022-3263(200012)65:26<9120:TSOAAU>2.0.ZU;2-3
Abstract
Convergent total syntheses of anhydrolycorinone, hippadine, and anhydrolyco rinium chloride are detailed, enlisting sequential inverse electron demand Diels-Alder reactions of an unsymmetrical N-acyl-6-amino-1,2,4,5-tetrazine.