Statistics of optical spectra from single-ring aggregates and its application to LH2

Citation
Mv. Mostovoy et J. Knoester, Statistics of optical spectra from single-ring aggregates and its application to LH2, J PHYS CH B, 104(51), 2000, pp. 12355-12364
Citations number
44
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF PHYSICAL CHEMISTRY B
ISSN journal
15206106 → ACNP
Volume
104
Issue
51
Year of publication
2000
Pages
12355 - 12364
Database
ISI
SICI code
1520-6106(200012)104:51<12355:SOOSFS>2.0.ZU;2-H
Abstract
We study the statistics of the optical spectra of individual ring-shaped mo lecular aggregates in which the site energies and transfer interactions are perturbed by both weak random disorder and a regular modulation due to a d eformation of the ring. Under these conditions, the spectrum is dominated b y two lines. We present an analytical expression for the joined probability distribution of the splitting between these lines and their average positi on. We compare our results to recent experiments performed on the bacterial antenna system LH2. Our analysis indicates the importance of intercomplex disorder.