One pot synthesis of a chiral N-phosphine substituted iminophosphorane: X-ray structure and in situ NMR study

Authors
Batsanov, AS Davidson, MG Fernandez, I Howard, JAK Lopez-Ortiz, F Price, RD
Citation
As. Batsanov et al., One pot synthesis of a chiral N-phosphine substituted iminophosphorane: X-ray structure and in situ NMR study, J CHEM S P1, (24), 2000, pp. 4237-4239
Citations number
27
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1
ISSN journal
14727781 → ACNP
Issue
24
Year of publication
2000
Pages
4237 - 4239
Database
ISI
SICI code
1472-7781(2000):24<4237:OPSOAC>2.0.ZU;2-Q
Abstract
An X-ray crystal structure reveals that the attempted deprotonation of cycl opropyl(triphenyl)phosphonium bromide with sodium amide affords a chiral N- phosphine substituted iminophosphorane via an unusual mechanism that has be en investigated by multi-nuclear and variable temperature in situ NMR spect roscopy.