We treat the organic system mMPYNN-BF4 as a network of hexagons. Each hexag
on contains six S = 1/2 spins coupled alternately with ferro- and antiferro
magnetic interactions. The antiferromagnetic coupling between hexagons is t
reated as a perturbation term. We obtain the ferro- and antiferromagnetic c
oupling constants in the hexagon and the antiferromagnetic coupling constan
t between hexagons. The susceptibility calculated by the second-order pertu
rbation method for mMPYNN-BF4 agrees well with the experimental results. Th
e ground state energy is also calculated.