Synthesis and characterisation of a bridging nitrido complex of titanium

Authors
Carmalt, CJ Mileham, JD White, AJP Williams, DJ
Citation
Cj. Carmalt et al., Synthesis and characterisation of a bridging nitrido complex of titanium, NEW J CHEM, 24(12), 2000, pp. 929-930
Citations number
18
Categorie Soggetti
Chemistry
Journal title
NEW JOURNAL OF CHEMISTRY
ISSN journal
11440546 → ACNP
Volume
24
Issue
12
Year of publication
2000
Pages
929 - 930
Database
ISI
SICI code
1144-0546(200012)24:12<929:SACOAB>2.0.ZU;2-S
Abstract
Titanium tetrachloride reacts with hexamethyldisilazane in the presence of 3,5-dimethylpyridine (L) to form a bridging nitrido species, [{Ti2Cl5(L)(5) }(mu -N)], the structure of which has been established by X-ray crystallogr aphy.