I. Matko et al., LOCAL ORDERING MODEL IN FE-SI-B AMORPHOUS-ALLOYS, Materials science & engineering. A, Structural materials: properties, microstructure and processing, 226, 1997, pp. 280-284
The main kinetics parameters of the crystallization of Fe80SixB20-x (w
ith x = 2, 4, 6, 8, 10) and Fe75Si15B10 glassy ribbons have been deter
mined using differential scanning calorimetry measurements. The struct
ure of the materials at various stages has been observed using transmi
ssion electron microscopy, electron and X-ray diffraction analysis. Th
e crystallization process in this system is found to consist of two di
stinct steps: individual steps represent complex processes from a stru
ctural point of view. The mechanism of crystallization is described in
terms of a local ordering (cluster) model, based on the role of the S
i atoms. (C) 1997 Elsevier Science S.A.