Ligand substituent effects on asymmetric induction. Effect of structural variations of the DIOP ligand on the Rh-catalyzed asymmetric hydrogenation of enamides

Authors
Yan, YY RajanBabu, TV
Citation
Yy. Yan et Tv. Rajanbabu, Ligand substituent effects on asymmetric induction. Effect of structural variations of the DIOP ligand on the Rh-catalyzed asymmetric hydrogenation of enamides, ORG LETT, 2(26), 2000, pp. 4137-4140
Citations number
30
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANIC LETTERS
ISSN journal
15237060 → ACNP
Volume
2
Issue
26
Year of publication
2000
Pages
4137 - 4140
Database
ISI
SICI code
1523-7060(200012)2:26<4137:LSEOAI>2.0.ZU;2-E
Abstract
[GRAPHICS] Substituent changes in the ligand (L*) backbone and the chelating phosphoru s atoms of the classical DIOP ligand result in dramatic changes in the enan tioselectivity of Rh+L*-catalyzed enamide hydrogenations.