Configurational ordering of cationic chiral dyes using a novel C-2-symmetric hexacoordinated phosphate anion

[GRAPHICS] C-2-Symmetry hexacoordinated phosphorus BINPHAT anion-of configuration cont rolled by a BINOL ligand-can be prepared readily in a one pot process and b ehaves as an efficient NMR chiral shift agent and chiral inducer onto monom ethinium dyes (CD, H-1 NMR).