Cross-coupling of highly pyramidalized alkenes: A straightforward access to functionalized tetrasecododecahedradienes

Authors
Camps, P Pujol, X Vazquez, S
Citation
P. Camps et al., Cross-coupling of highly pyramidalized alkenes: A straightforward access to functionalized tetrasecododecahedradienes, ORG LETT, 2(26), 2000, pp. 4225-4228
Citations number
40
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANIC LETTERS
ISSN journal
15237060 → ACNP
Volume
2
Issue
26
Year of publication
2000
Pages
4225 - 4228
Database
ISI
SICI code
1523-7060(200012)2:26<4225:COHPAA>2.0.ZU;2-K
Abstract
[GRAPHICS] The synthesis and chemical trapping of a highly pyramidalized pentacyclo[6. 4.0.0(2,10).0(3,7).0(4,9)]dodec-8-ene containing ketal functions is reporte d. Its cross-coupling reaction with 3,7-dimethyltricyclo[3.3.0.0(3,7)]oct-1 (5)-ene followed by a [2 + 2] retrocycloaddition reaction gives a straightf orward access to functionalized tetrasecododecahedradienes.