Gf. Zhou et al., LASER-INDUCED CRYSTALLIZATION IN GE-SB-TE OPTICAL-RECORDING MATERIALS, Materials science & engineering. A, Structural materials: properties, microstructure and processing, 226, 1997, pp. 1069-1073
Laser-induced crystallization behaviour in Ge-Sb-Te optical recording
thin film materials, that are sandwiched between dielectric layers, wa
s studied by a multipulse laser technique. The reflection changes at 7
80 nm laser wavelength caused by local heating by a pulsed high-power
laser beam are monitored. Both the nucleation time and the complete cr
ystallization time are found to decrease significantly with increasing
phase change layer thickness up to about 25 nm, above which both tend
to become constant. Furthermore, the maximum crystallization speed de
pends on the type of dielectric material. The strong dependence of cry
stallization speed on layer thickness is explained in terms of competi
ng interface and bulk processes. This finding is of practical use beca
use it allows the design of phase change optical recording media which
can be used at high linear recording speeds. (C) 1997 Elsevier Scienc
e S.A.