Complex formation between chlorine dioxide and 2,2,6,6-tetramethylpiperidin-1-oxyl

Authors
Ganiev, IM Shereshovets, VV Grigor'ev, IA Tolstikov, GA
Citation
Im. Ganiev et al., Complex formation between chlorine dioxide and 2,2,6,6-tetramethylpiperidin-1-oxyl, RUSS CHEM B, 49(10), 2000, pp. 1687-1690
Citations number
12
Categorie Soggetti
Chemistry
Journal title
RUSSIAN CHEMICAL BULLETIN
ISSN journal
10665285 → ACNP
Volume
49
Issue
10
Year of publication
2000
Pages
1687 - 1690
Database
ISI
SICI code
1066-5285(200010)49:10<1687:CFBCDA>2.0.ZU;2-2
Abstract
The complex formation of ClO2 with 2,2,6,6-tetramethylpiperidin-1-oxyl (TMP O) in acetone, acetonitrile, n-heptane, diethyl ether, carbon tetrachloride , and toluene was studied spectrophotometrically at -20 to +20 degreesC. Th e thermodynamic parameters of complex formation were determined at 20 degre esC. The transformation of the complex into the oxoammonium salt TMPO+ClO2- was found.