Synthesis of 5-organo-, 9-organo-, and 9,11-diorgano-nido-7,8-dicarbaundecaborane salts by cross-coupling

Authors
Zakharkin, LI Ol'shevskaya, VA Petrovskii, PV
Citation
Li. Zakharkin et al., Synthesis of 5-organo-, 9-organo-, and 9,11-diorgano-nido-7,8-dicarbaundecaborane salts by cross-coupling, RUSS J G CH, 70(5), 2000, pp. 678-682
Citations number
10
Categorie Soggetti
Chemistry
Journal title
RUSSIAN JOURNAL OF GENERAL CHEMISTRY
ISSN journal
10703632 → ACNP
Volume
70
Issue
5
Year of publication
2000
Pages
678 - 682
Database
ISI
SICI code
1070-3632(200005)70:5<678:SO59A9>2.0.ZU;2-6
Abstract
5-Iodo-nido-7,8-dicarbaundecaborane salts containing the iodine atom in the polyhedron skeleton, as well as 9-iodo- and 9,11-diiodo-rtido-7,8-dicarbau ndecaborates containing iodine atoms at the boron atoms in the pentagonal p lane of the polyhedron, enter into cross-coupling with organomagnesium comp ounds, catalyzed by palladium complexes, to give 5-organo-, 9-organo-, and 9,11-diorgano-nido-7,8-dicarbaundecaborane salts.