Reaction of dichlorophosphines with glycidol. New data on the transformations of cyclic phosphonates

Authors
Bredikhin, AA Lazarev, SN Efremov, YY Sharafutdinova, DR Bredikhina, ZA
Citation
Aa. Bredikhin et al., Reaction of dichlorophosphines with glycidol. New data on the transformations of cyclic phosphonates, RUSS J G CH, 70(5), 2000, pp. 708-713
Citations number
14
Categorie Soggetti
Chemistry
Journal title
RUSSIAN JOURNAL OF GENERAL CHEMISTRY
ISSN journal
10703632 → ACNP
Volume
70
Issue
5
Year of publication
2000
Pages
708 - 713
Database
ISI
SICI code
1070-3632(200005)70:5<708:RODWGN>2.0.ZU;2-D
Abstract
Reaction of dichlorophosphines with glycidol yields 2-R-4-chloromethyl-1,3, 2-dioxaphospholanes as primary products, which under the reaction condition s or under the action of HCL surprisingly readily undergo redox transformat ions yielding 2-R-4-chloromethyl-1,3,2-dioxaphospholane 2-oxides, dichlorop ropyl R-phosphinates, bis(dichloropropyl) R-phosphonates, and phosphines RP H2.