Role of acid-base interactions in complexation of tetrahalotetraazaporphyrins with magnesium acetate in the system dimethyl sulfoxide-chlorobenzene

Authors
Petrov, OA Chizhova, NV Berezin, BD Syrbu, SA
Citation
Oa. Petrov et al., Role of acid-base interactions in complexation of tetrahalotetraazaporphyrins with magnesium acetate in the system dimethyl sulfoxide-chlorobenzene, RUSS J G CH, 70(5), 2000, pp. 771-777
Citations number
19
Categorie Soggetti
Chemistry
Journal title
RUSSIAN JOURNAL OF GENERAL CHEMISTRY
ISSN journal
10703632 → ACNP
Volume
70
Issue
5
Year of publication
2000
Pages
771 - 777
Database
ISI
SICI code
1070-3632(200005)70:5<771:ROAIIC>2.0.ZU;2-1
Abstract
The kinetics of complexation of magnesium acetate with tetrachloro- and tet rabromotetraazaporphine in the system dimethyl sulfoxide-chlorobenzene was studied. Acid-base interactions play an important role in this reaction. Po ssible mechanisms of formation of the metal complex were suggested.