Epoxidation of olefins mediated by aliphatic ketiminium salts

Authors
Minakata, S Takemiya, A Nakamura, K Ryu, I Komatsu, M
Citation
S. Minakata et al., Epoxidation of olefins mediated by aliphatic ketiminium salts, SYNLETT, (12), 2000, pp. 1810-1812
Citations number
34
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
SYNLETT
ISSN journal
09365214 → ACNP
Issue
12
Year of publication
2000
Pages
1810 - 1812
Database
ISI
SICI code
0936-5214(200012):12<1810:EOOMBA>2.0.ZU;2-3
Abstract
An aliphatic ketiminium salt derived from pyrrolidine and cyclohexanone was found to be a good mediator for epoxidation of a variety of olefins. The c hiral ketiminium salt 2 was applicable to asymmetric epoxidation.