Stereoselective synthesis of highly oxygenated cyclohexanes through a [3+3] annulation approach

Authors
Sharma, GVM Prasad, TR Krishna, PR Krishnudu, K Rao, MHVR Kunwar, AC
Citation
Gvm. Sharma et al., Stereoselective synthesis of highly oxygenated cyclohexanes through a [3+3] annulation approach, TETRAHEDR-A, 11(22), 2000, pp. 4499-4507
Citations number
14
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON-ASYMMETRY
ISSN journal
09574166 → ACNP
Volume
11
Issue
22
Year of publication
2000
Pages
4499 - 4507
Database
ISI
SICI code
0957-4166(20001117)11:22<4499:SSOHOC>2.0.ZU;2-4
Abstract
The synthesis of highly oxygenated cyclohexanes has been achieved through a Michael-Wittig protocol via a [3+3] annulation of the enal that is derived from,,3-O-isopropylidene-(R)-glyceraldehyde. The gamma -alkoxy enal system is responsible for the stereoselectivity. (C) 2000 Elsevier Science Ltd. A ll rights reserved.