A new technique - low-pressure plasma spray (LPPS) - has been used for depo
sition of high quality Al2O3 coatings on aluminum substrates for many diffe
rent applications. The initial results on the properties and structure of t
he LPPS alumina coating are presented in this paper. Chemical compositional
analysis using secondary neutral mass spectroscopy (SNMS) has shown that t
he coatings are close to stoichiometric with an oxygen to aluminum ratio of
1.65. The cross-sectional transmission electron microscopy and X-ray diffr
action investigations revealed that the structure of the coating is complex
: layered splat structure with splats consisting of a polycrystalline core
embedded in an amorphous matrix. Initial dielectric strength measurements s
how dielectric strengths of approximately 1000 kV/cm in some of the thinner
(10-20 mum) LPPS coatings, a value significantly higher than in other ther
mal spray coatings. The dielectric strength of these LPPS coatings is relat
ed to the microstructure as determined by electron microscopy imaging. The
studies of the adhesion of the coating to the aluminum substrate using scra
tch testing with a 5-mm ball indentor showed maximum adhesion (critical loa
ds) for the 20-mum thick LPPS coatings. These adhesion data have been relat
ed to the microstructure of the coatings and the initial substrate preparat
ion. The effect of different substrate preparation on improving adhesion is
being investigated together with wear testing of the LPPS coatings. (C) 20
00 Elsevier Science B.V. All rights reserved.