We have studied the optical properties of surface quantum wells with differ
ent width of wells (5nm and 10nm) by means of In-situ photo-modulated refle
ctance(PR) spectroscopy on a molecular beam epitaxy system. The surface qua
ntum well is confined on one side by the vacuum and on the other side by Al
xGa1-xAs barrier. In experiments, we have observed clearly the transitions
between the confined heavy and light hole states to the confined electron s
tates. The transitions of the excited states in 10nm surface quantum well a
re observed at first. The effects of the surface on the confined states hav
e been well studied by combination of the PR spectra and the effective mass
approximation theory.