Synthesis and microwave properties of Tl2Ba2CaCu2O8 superconducting films grown by MOCVD

We report on the synthesis, structural and electrical characterization of h igh quality Tl2Ba2Ca1Cu2O8 (T1-2212) superconducting films. The samples hav e been grown ex-situ on 10 x 10 mm LaAlO3 (100) substrates by a combined ap proach of metal-organic chemical vapor deposition (MOCVD) and thallium vapo r diffusion. The morphological and compositional nature of the c-axis orien ted films has been investigated by SEM and X-ray analyses. Typical values o f T-c = 104 K and J(c) = 0.5 MA/cm(2) at 77 K have been measured. Microwave measurements have been performed at f = 87 GHz inserting time film in a co pper cavity and at f = 1.5 GHz on patterned samples using a microstrip reso nator technique. A generation depth lambda (0) = 400 nm is evaluated by fit ting the microwave data with phenomenological equations. The minimum value of the surface resistance R-s measured at 4.2 K is 60 mu Omega and 0 m Omeg a at 1.5 GHz and 87 GHz respectively. The microwave data are described in t he context of a modified two fluid model. An evaluation of the temperature dependence of the scattering rate has been performed through the simultaneo us measurement of the surface resistance and the penetration depth.