Correlation between the viscoelastic properties of a soft crystal and its microstructure

We investigate the rheological properties of a cubic fee phase of micelles obtained by aggregation of a triblock copolymer (PEO)(127)(PPO)(48)(PEO)(12 7) in water as selective solvent. The resulting soft solid is submitted to a range of stresses varying from 20 to 800 Pa in Couette geometry. Creep an d flow behaviour can be distinguished and interpreted in terms of structura l changes previously observed by SAXS under flow. Contrasting with other sy stems, no discontinuity in the flow behaviour is associated with the struct ural changes. The strong shear thinning is interpreted from the scattering data, as resulting from the nucleation of a new structure of hexagonal comp act planes parallel to the Couette walls. This creates a lubricating domain in the gap, whose size grows with the applied shear rate. We argue moreove r that the very existence of flow (as a steady state opposed to creep) is a ssociated with this so-called layer-sliding structure in a fraction, howeve r small, of the sample.