DEPROTONATION OF METAL-COORDINATED WATER IN A SOLID-LIQUID SYSTEM - ACONVENIENT SYNTHESIS OF THE (MU-OXO)BIS[TRICHLOROFERRATE(III)] DIANION, [FE2OCL6](2-)

Authors
DELLAMICO DB CALDERAZZO F LABELLA L MARCHETTI F QUADRELLI EGF
Citation
Db. Dellamico et al., DEPROTONATION OF METAL-COORDINATED WATER IN A SOLID-LIQUID SYSTEM - ACONVENIENT SYNTHESIS OF THE (MU-OXO)BIS[TRICHLOROFERRATE(III)] DIANION, [FE2OCL6](2-), Gazzetta chimica italiana, 127(2), 1997, pp. 103-106
Citations number
68
Categorie Soggetti
Chemistry
Journal title
Gazzetta chimica italiana → ACNP
ISSN journal
00165603
Volume
127
Issue
2
Year of publication
1997
Pages
103 - 106
Database
ISI
SICI code
0016-5603(1997)127:2<103:DOMWIA>2.0.ZU;2-5
Abstract
A high-yield one-step synthesis of the dinuclear (mu-oxo)bis[trichloro ferrate(III)] anion, [Fe2OCl6](2-), as [amH](2)[Fe2OCl6] or [pyH](2)[F e2OCl6], is reported consisting of treating anhydrous iron(III) chlori de with the stoicheiometric amount of FeCl3 . 6 H2O in toluene as medi um in the presence of a secondary amine (am) or pyridine (py), in a so lid-liquid system.