The increasingly stringent and expanding array of regulatory controls to re
duce potentially toxic emissions associated with waste burning ave driving
the cleanup of these emissions away from the usually costly rudimentary pra
ctices to systems in which the cleanup process can be efficiently controlle
d and modified to accommodate changes In regulatory requirements. The techn
ology of first: choice is the Dry Sorbent Injection (DSI) of flue gases. In
this work, the collection efficiency of a volatile organic compound (VOC)
from flue gases on a powdered activated carbon adsorbent is investigated. R
esults from pilot scale tests ave compared with the results generated from
a theoretical model developed for DSI. The model uses a transient diffusion
equation for particles with adsorption represented using a Freundlich isot
herm and a balance equation for the bulk gas phase VOC fraction. The cases
of injection of adsorbing particles using the geometrical mean diameter and
the actual particle size distribution are investigated.