The adsorption capacities of carbon dioxide on six commercial hydrotalcite-
like compounds and the main factors (aluminum content, anion type, water co
ntent, and heat treatment temperature) influencing their adsorption capacit
y at high temperatures have been investigated using a gravimetric technique
. There is an optimum aluminum content and heat treatment temperature for t
he adsorption capacity. The carbonate anion favors adsorption of carbon dio
xide compared to OH-, and a low content of water also improves the adsorpti
on capacity. The carbon dioxide adsorption capacity is mainly dependent on
the microporous volume, interlayer spacing, and layer charge density of the
hydrotalcite-like compounds.