Adsorption of carbon dioxide onto hydrotalcite-like compounds (HTlcs) at high temperatures

Citation
Z. Yong et al., Adsorption of carbon dioxide onto hydrotalcite-like compounds (HTlcs) at high temperatures, IND ENG RES, 40(1), 2001, pp. 204-209
Citations number
30
Categorie Soggetti
Chemical Engineering
Journal title
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
ISSN journal
08885885 → ACNP
Volume
40
Issue
1
Year of publication
2001
Pages
204 - 209
Database
ISI
SICI code
0888-5885(20010110)40:1<204:AOCDOH>2.0.ZU;2-H
Abstract
The adsorption capacities of carbon dioxide on six commercial hydrotalcite- like compounds and the main factors (aluminum content, anion type, water co ntent, and heat treatment temperature) influencing their adsorption capacit y at high temperatures have been investigated using a gravimetric technique . There is an optimum aluminum content and heat treatment temperature for t he adsorption capacity. The carbonate anion favors adsorption of carbon dio xide compared to OH-, and a low content of water also improves the adsorpti on capacity. The carbon dioxide adsorption capacity is mainly dependent on the microporous volume, interlayer spacing, and layer charge density of the hydrotalcite-like compounds.