Heteroleptic phthalocyaninato-[2,3,9,10,16,17,23,24-octakis(octyloxy)phthalocyaninato] rare earth(III) triple-deckers: synthesis and spectroscopic characterization

Authors
Liu, W Jiang, JZ Pan, N Arnold, DP
Citation
W. Liu et al., Heteroleptic phthalocyaninato-[2,3,9,10,16,17,23,24-octakis(octyloxy)phthalocyaninato] rare earth(III) triple-deckers: synthesis and spectroscopic characterization, INORG CHIM, 310(2), 2000, pp. 140-146
Citations number
36
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANICA CHIMICA ACTA
ISSN journal
00201693 → ACNP
Volume
310
Issue
2
Year of publication
2000
Pages
140 - 146
Database
ISI
SICI code
0020-1693(200012)310:2<140:HP>2.0.ZU;2-B
Abstract
The homo-dinuclear heteroleptic phthalocyaninato-[2,3,9,10,16,17,23,24-octa kis(octyloxy)phthalocyaninato] rare earth(III) triple-decker complexes (Pc) M[Pc(OC8H17)(8)]M[Pc(OC8H17)(8)] (M = Pr, Nd, Sm, Eu, Tb, Dy, Y, Ho, Er, Tm ) (1a-10a) and (Pc)M[Pc(OC8H17)(8)]M(Pc) (M = Nd, Sm, Eu, Tb, Dy, Y, Ho, Er , Tm) (2b-10b) were obtained by condensation of bis(phthalocyaninato) rare earths M[Pc(OC8H17)(8)](2) (M = Pr, Nd, Sm, Eu, Tb, Dy, Y, Ho, Er, Tm), Li- 2(Pc) and M(acac)(3). nH(2)O (M = Pr, Nd, Sm. Eu, Tb, Dy, Y, Ho, Er, Tm). T hese novel compounds were characterized by H-1 NMR, mass, electronic absorp tion (UV-Vis). and IR spectroscopic methods. (C) 2000 Elsevier Science B.V. All rights reserved.