The deformation and fracture behaviour of some commercial acrylic bone
cements have been investigated. Cements were characterized by gel per
meation chromatography, dynamic mechanical analysis and scanning elect
ron microscopy. The influence of liquid to powder ratio, curing temper
ature, strain rate and non-reacted monomer was analysed for one radiol
ucent cement. Results showed that the beta transition activation proce
ss influences both deformation and fracture behaviour. Fracture surfac
e stress whiteness revealed the presence of crazes as the main plastic
deformation mechanism. Non-reacted monomer acted as a plasticizer lea
ding to materials with lower yield strength, sigma(y), that induces cr
ack tip blunting and improves toughness. It appears that the presence
of radio-pacifier fillers also improves fracture toughness by promotin
g interactions between the crack and the second phase dispersion.