Influence of TDI concentration on the properties of unsaturated polyester resins

Citation
B. Gawdzik et al., Influence of TDI concentration on the properties of unsaturated polyester resins, J APPL POLY, 79(7), 2001, pp. 1201-1206
Citations number
17
Categorie Soggetti
Organic Chemistry/Polymer Science","Material Science & Engineering
Journal title
JOURNAL OF APPLIED POLYMER SCIENCE
ISSN journal
00218995 → ACNP
Volume
79
Issue
7
Year of publication
2001
Pages
1201 - 1206
Database
ISI
SICI code
0021-8995(20010214)79:7<1201:IOTCOT>2.0.ZU;2-O
Abstract
Three different unsaturated polyester resins were modified by toluene diiso cyanate (TDI). All the resins studied were commercially available. One, 2, and 3% additions of TDI caused important changes of the resins properties. With an increase of TDI concentration gelation times increased. Suppression of the exotherm peaks-desired effect from practical point of view-was obse rved. Unfortunately, increase of TDI concentration caused enormous increase of the resins viscosity. Additionally the resins with 3% of TDI exhibit th ixotropic properties. (C) 2000 John Wiley & Sons, Inc.