Time-of-flight SIMS as a useful technique for the study of the influence of carbon black in natural rubber vulcanization

Authors
Borros, S Vidal, E Agullo, N van Ooij, WJ
Citation
S. Borros et al., Time-of-flight SIMS as a useful technique for the study of the influence of carbon black in natural rubber vulcanization, KAUT GUM KU, 53(12), 2000, pp. 711-715
Citations number
12
Categorie Soggetti
Material Science & Engineering
Journal title
KAUTSCHUK GUMMI KUNSTSTOFFE
ISSN journal
09483276 → ACNP
Volume
53
Issue
12
Year of publication
2000
Pages
711 - 715
Database
ISI
SICI code
0948-3276(200012)53:12<711:TSAAUT>2.0.ZU;2-G
Abstract
The use of TOFSIMS technique to analyze the carbon black surface during the squalene vulcanization reaction has been demonstrated to be a useful techn ique to follow the sulfur vulcanization kinetics. The results obtained are in agreement with those using the classic techniques HPLC and GPC, The resu lts show that the intermediate compounds are strongly adsorbed on the carbo n black surface.