Au particles were prepared by evaporation in ultra high vacuum at high temp
erature, on the surfaces of TiO2 micro-spheres with the anatase structure.
The morphology and the structural deformation in Au deposits were studied b
y high resolution transmission electron microscopy and image simulations by
the multislice technique. The particles were polyhedral, limited by (100)
and (111) faces. Patches with a hexagonal lattice were found around the par
ticles, which was interpreted as thin Au islands on the surface. In these i
slands the Au lattice was deformed and perfectly accommodated to the (110)
surface of TiO2. (C) 2001 Elsevier Science B.V. All rights reserved.