The sputtering of alloy surfaces with Ar+ ions may change their chemical co
mposition by preferentially removing particular atomic species. For the ico
sahedral quasicrystal Al-Pd-Mn this produces reversible surface phase trans
itions either to a cubic structure or to a decagonal quasicrystal, dependin
g on the temperature. In both the cases, the original icosahedral structure
is restored upon annealing. We discuss the orientation of these phases rel
ative to the underlying icosahedral bulk and the processes responsible for
the restoration of the icosahedral structure. (C) 2000 Elsevier Science B.V
. All rights reserved.