GeCl(2)(.)dioxane reacts with 1 and 2 equiv of [2,4-di-tert-butyl-6-(tert-b
utoxymethyl)lithium (t-BomxLi) to give the germanium(II) compounds t-BomxGe
Cl(1) and [t-Bomx](2)Ge (2), respectively. Reaction with 2 equiv of [2,4-di
-tert-butyl-6-(iso-propoxymethyl)phenyl]lithium (i-PomxLi) affords [i-Pomx]
(2)Ge (3). Compounds 1-3 show intramolecular coordination of the alkoxy lig
and to the germanium(II) center. The use of the 2,4-di-tert-butyl-6(methoxy
methyl)phenyl ligand (Momx) does not lead to the expected base-stabilized g
ermanium(II) species Momx(2)Ge but gives the germanium(IV) compound MomxGe[
OCH2(2,4-di-tert-butylphenyl)] (Me) (4) as the result of an intramolecular
O-CH3 bond oxidative addition process; X-ray crystal structure determinatio
ns are presented for 1, 2, and 4.