Citation
K. Miqueu et al., Gas-phase thermolysis of phosphine-borane complexes studied by helium I photoelectron spectroscopy, ORGANOMETAL, 20(1), 2001, pp. 143-147
Citations number
22
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333
→ ACNP
Volume
20
Issue
1
Year of publication
2001
Pages
143 - 147
Database
ISI
SICI code
0276-7333(20010108)20:1<143:GTOPCS>2.0.ZU;2-F
Abstract
Flash vacuum thermolysis (FVT) of cyclic phosphine-borane complexes and dir
ect analysis of the gaseous flow by ultraviolet photoelectron spectroscopy
allowed us to characterize transient phosphinoboranes and to provide inform
ation about their electronic properties. This study was also supported by H
RMS results. Ab initio calculations with the hybrid functional B3LYP and th
e basis set 6-311G (d, p) allowed us to assign the different ionizations of
the PE spectra and provided more information about the character of the BP
bond.