The reaction of beta -diketones, ethylacetoacetate and malononitrile with a
lpha, beta -insaturated beta, beta -difunctionnalized phosphonates constitu
tes a performant new route leading to the formation of substituted 2-amino-
4-phosphono-4H-pyranes.
Moreover the reaction of dialkylphosphonates with 2-hydroxybenzylidenemalon
onitrile affords a new series of phosphorylated benzopyranes.