Oxidative deprotection of trimethylsilyl and tetrahydropyranyl ethers and ethylene acetals with benzyltriphenylphosphonium peroxomonosulfate in the presence of bismuth chloride under non-aqueous conditions
Ar. Hajipour et al., Oxidative deprotection of trimethylsilyl and tetrahydropyranyl ethers and ethylene acetals with benzyltriphenylphosphonium peroxomonosulfate in the presence of bismuth chloride under non-aqueous conditions, PHOSPHOR SU, 165, 2000, pp. 155-163
Citations number
26
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
Benzyltriphenylphosphonium peroxomonosulfate (BnPh3P+HSO5-) (1) is used as
a new reagent for oxidative deprotection of trimethylsilyl and tctrahydropy
ranyl ethers and ethylene acetals to afford carbonyl compounds in refluxing
acetonitrile in the presence of bismuth chloride.