F. Ancilotto et al., Wetting transitions of He-4 on alkali-metal surfaces from density-functional calculations, PHYS REV B, 62(24), 2000, pp. 17035-17042
We have studied the wetting properties of He-4 adsorbed on the surface of h
eavy alkali metals by using a nonlocal free-energy density functional which
describes accurately the surface properties of liquid He-4 in the temperat
ure range 0<T<3 K. Our results for He-4 on the Cs surface give both the tem
perature dependence of the contact angle and the wetting temperature in goo
d agreement with the experimental findings. For the He-4/Rb system we find
that a wetting transition on the Rb surface occurs at T similar to1.4 K, wh
ereas;the experiments show either wetting down to T=0 or a wetting transiti
on at T similar to0.3,K; We suggest that this disagreement is due either to
an inaccuracy of the fluid-substrate potential used in our calculations or
the consequence of substrate roughness, which is known to affect the Rb su
rface, and whose effect would be to lower the wetting temperature. The sens
itivity of the wetting transition to the He-surface potential is stressed f
or the He/Rb surface, which may justify the controversial experimental find
ings for this system.