Optical properties of nanodiamond layers

Thin ultradisperse diamond (UDD) layers deposited from a water suspension a re studied by optical and x-ray photoelectron spectroscopy (XPS). The effec tive band gap determined by the 10(4)-cm(-1) criterion for ozone-cleaned UD D is 3.5 eV. The broad structureless photoluminescence band (380-520 nm) is associated with radiative recombination through a system of continuously d istributed energy levels in the band gap of diamond nanoclusters. The optic al absorption of the material at 250-1000 nm originates from absorption on the disordered nanocluster surface containing threefold-coordinated carbon. The surface of UDD clusters subjected to acid cleaning contains nitrogen-o xygen complexes adsorbed in the form of NO3- nitrate ions. Annealing in a h ydrogen atmosphere results in desorption of the nitrate ions from the clust er surface. The evolution of the oxygen (O1s) and nitrogen (N1s) lines in t he XPS spectra under annealing of a UDD layer is studied comprehensively. ( C) 2001 MAIK "Nauka/Interperiodica".