Tf. Irzhak et Vi. Irzhak, Method of mathematical description of the kinetics of living radical polymerization, POLYM SCI A, 42(12), 2000, pp. 1332-1336
The kinetics of living radical polymerization is described by the method of
moments, which allows one to solve kinetic problems of various complexitie
s: material and other initiation, the introduction of radical accepters or
previously synthesized complexes, monomers (oligomers) of any functionality
, and any mechanism of chain termination. As an example, the process of lin
ear polymerization with a material initiation and chain termination by reco
mbination is analyzed.