Method of mathematical description of the kinetics of living radical polymerization

Citation
Tf. Irzhak et Vi. Irzhak, Method of mathematical description of the kinetics of living radical polymerization, POLYM SCI A, 42(12), 2000, pp. 1332-1336
Citations number
6
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
POLYMER SCIENCE SERIES A
ISSN journal
0965545X → ACNP
Volume
42
Issue
12
Year of publication
2000
Pages
1332 - 1336
Database
ISI
SICI code
0965-545X(200012)42:12<1332:MOMDOT>2.0.ZU;2-5
Abstract
The kinetics of living radical polymerization is described by the method of moments, which allows one to solve kinetic problems of various complexitie s: material and other initiation, the introduction of radical accepters or previously synthesized complexes, monomers (oligomers) of any functionality , and any mechanism of chain termination. As an example, the process of lin ear polymerization with a material initiation and chain termination by reco mbination is analyzed.