The structure of pseudopolymeric H complexes of dimethyl dihydrogen 3,3',4,
4'-benzophenonetetracarboxylate with various diamines, which are initial su
bstances in preparation of polyimide foams, was studied by C-13 NMR spectro
scopy. The chemical structure of various model H complexes was studied usin
g AMI quantum-chemical calculations. The supramolecular structure of H comp
lexes was studied by X-ray diffraction in the solid phase and by a rheologi
cal method in the melt.