H complexes of dimethyl dihydrogen benzophenonetetracarboxylate with various diamines

Citation
Vn. Artem'Eva et al., H complexes of dimethyl dihydrogen benzophenonetetracarboxylate with various diamines, RUS J AP CH, 73(7), 2000, pp. 1242-1248
Citations number
20
Categorie Soggetti
Chemistry
Journal title
RUSSIAN JOURNAL OF APPLIED CHEMISTRY
ISSN journal
10704272 → ACNP
Volume
73
Issue
7
Year of publication
2000
Pages
1242 - 1248
Database
ISI
SICI code
1070-4272(200007)73:7<1242:HCODDB>2.0.ZU;2-7
Abstract
The structure of pseudopolymeric H complexes of dimethyl dihydrogen 3,3',4, 4'-benzophenonetetracarboxylate with various diamines, which are initial su bstances in preparation of polyimide foams, was studied by C-13 NMR spectro scopy. The chemical structure of various model H complexes was studied usin g AMI quantum-chemical calculations. The supramolecular structure of H comp lexes was studied by X-ray diffraction in the solid phase and by a rheologi cal method in the melt.