Reaction of pentaphenylantimony with triphenylbismuth diacylates

Citation
Vv. Sharutin et al., Reaction of pentaphenylantimony with triphenylbismuth diacylates, RUSS J G CH, 70(6), 2000, pp. 873-875
Citations number
11
Categorie Soggetti
Chemistry
Journal title
RUSSIAN JOURNAL OF GENERAL CHEMISTRY
ISSN journal
10703632 → ACNP
Volume
70
Issue
6
Year of publication
2000
Pages
873 - 875
Database
ISI
SICI code
1070-3632(200006)70:6<873:ROPWTD>2.0.ZU;2-Y
Abstract
Reactions of pentaphenylantimony with triphenylbismuth diacylates yield the corresponding tetraphenylantimony acylates. Triphenylbismuth bis(trichloro acetate) was prepared by oxidation of triphenylbismuth with hydrogen peroxi de in the presence of trichloroacetic acid. The structure of triphenylbismu th dibenzoate was determined by single crystal X-ray diffraction. The coord ination polyhedron of the central atom is intermediate between trigonal bip yramid and pentagonal bipyramid; the benzoate groups occupy the equatorial position.