Comparison of the mass spectral fragmentation pathways of organochlorogermanes and organochlorosilanes

Authors
Bochkarev, VN Khromykh, NN Bykovchenko, VG Komalenkova, NG Shcherbinin, VV Chernyshev, EA
Citation
Vn. Bochkarev et al., Comparison of the mass spectral fragmentation pathways of organochlorogermanes and organochlorosilanes, RUSS J G CH, 70(6), 2000, pp. 897-901
Citations number
14
Categorie Soggetti
Chemistry
Journal title
RUSSIAN JOURNAL OF GENERAL CHEMISTRY
ISSN journal
10703632 → ACNP
Volume
70
Issue
6
Year of publication
2000
Pages
897 - 901
Database
ISI
SICI code
1070-3632(200006)70:6<897:COTMSF>2.0.ZU;2-N
Abstract
Propyl-, butyl-, vinyl-, clorophenyl-, and phenyltrichlorogermanes under el ectron impact decompose by channels different from those characteristic of the corresponding silanes. Methyl-, ethyl-, allyltri-chlorogermanes, and vi nyldichlorogermane decompose in the same way as the corresponding silanes. Fragmentation pathways of the organochlorogermanes and organochlorosilanes studied are proposed.