1-Morpholino-3,3-dimethyl-3,4-dihydroisoquinoline complex with copper(II) nitrate

Authors
Sokol, VI Ryabov, MA Merkur'eva, NY Sergienko, VS Davydov, VV Shklyaev, YV
Citation
Vi. Sokol et al., 1-Morpholino-3,3-dimethyl-3,4-dihydroisoquinoline complex with copper(II) nitrate, RUSS J IN C, 45(12), 2000, pp. 1834-1840
Citations number
8
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
ISSN journal
00360236 → ACNP
Volume
45
Issue
12
Year of publication
2000
Pages
1834 - 1840
Database
ISI
SICI code
0036-0236(200012)45:12<1834:1CWCN>2.0.ZU;2-D
Abstract
The complex (LH)(2)[Cu(NO3)(4)], where L is 1-morpholino-3,3-dimethyl-3,4-d ihydroisoquinoline, is synthesized and characterized by X-ray crystallograp hy and IR and electronic spectroscopy. The complex has a cationic-anionic s tructure. The organic ligand is protonated at the nitrogen atom of the dihy droisoquinoline moiety. The LH+ cations and [Cu(NO3)(4)](2-) anions are lin ked by N-H . . .O hydrogen bonds. Of the four nitrate groups, one is coordi nated monodentate, one is bidentate, and two are anisobidentate.