Synthesis and crystal structure of rubidium dimolybdouranylate monohydrateRb2UO2(MoO4)(2) center dot H2O

Authors
Khrustalev, VN Andreev, GB Antipin, MY Fedoseev, AM Budantseva, NA Shirokova, IB
Citation
Vn. Khrustalev et al., Synthesis and crystal structure of rubidium dimolybdouranylate monohydrateRb2UO2(MoO4)(2) center dot H2O, RUSS J IN C, 45(12), 2000, pp. 1845-1847
Citations number
9
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
ISSN journal
00360236 → ACNP
Volume
45
Issue
12
Year of publication
2000
Pages
1845 - 1847
Database
ISI
SICI code
0036-0236(200012)45:12<1845:SACSOR>2.0.ZU;2-1
Abstract
The crystal structure of the complex Rb2UO2(MoO4)(2).H2O is determined. The crystal data are the following: a = 7.967(3) Angstrom, b = 10.956(4) Angst rom, c = 13.679(5) Angstrom, beta = 96.69(3)degrees, V = 1185.7(8) Angstrom (3), space group P2(1)/c, Z = 4, d(calcd) = 4.363 g/cm(3), R = 0.064, R-W = 0.147. The crystal structure is layered; water of crystallization is not involved in the coordination sphere of the uranium atom.