Synthesis and crystal structure of 1,7-(NH3)(2)B12H10 center dot 0.5H(2)O

Authors
Dudenkov, IV Zhizhin, KY Chernyavskii, AS Katser, SB Goeva, LV Sergienko, VS Solntsev, KA Kuznetsov, NT
Citation
Iv. Dudenkov et al., Synthesis and crystal structure of 1,7-(NH3)(2)B12H10 center dot 0.5H(2)O, RUSS J IN C, 45(12), 2000, pp. 1864-1867
Citations number
5
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
ISSN journal
00360236 → ACNP
Volume
45
Issue
12
Year of publication
2000
Pages
1864 - 1867
Database
ISI
SICI code
0036-0236(200012)45:12<1864:SACSO1>2.0.ZU;2-0
Abstract
1,7-Diaminoundecahydro-closo-dodecaborate was synthesized and characterized . Crystals are orthorhombic, space group Pna2(1), a = 22.99(1) Angstrom, b = 10.293(6) Angstrom, c = 9.323(6) Angstrom, V = 2206(2) Angstrom (3), Z = 8. Crystals contain two independent identical neutral molecules 1,7-(NH3)(2 )B12H10 and one water molecule of crystallization. The arrangement of the N H3 substituents corresponds to the meta isomer.