We report dependences of electrical properties on SiH4/H-2 dilution rate an
d film thickness for microcrystalline silicon films formed by a hydrogen ra
dical-induced chemical vapor deposition (HRCVD) method. The electrical cond
uctivity of the films at SiH4 18 sccm/H-2 120 seem was markedly increased t
o 10(-3) S/cm as film thickness increased above 100 nm. Crystalline grains
with (220) orientation were formed. Theoretical analysis revealed that grai
n boundaries among (220) grains had a low defect density of 1 x 10(12) cm(-
2) so that the high conductivity was achieved. (C) 2001 Elsevier Science B.
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