Polynuclear complexes of copper(I) halides: Coordination chemistry and catalytic transformations of alkynes

Authors
Mykhalichko, BM Temkin, ON Mys'kiv, MG
Citation
Bm. Mykhalichko et al., Polynuclear complexes of copper(I) halides: Coordination chemistry and catalytic transformations of alkynes, USP KH, 69(11), 2000, pp. 1042-1070
Citations number
151
Categorie Soggetti
Chemistry
Journal title
USPEKHI KHIMII
ISSN journal
00421308 → ACNP
Volume
69
Issue
11
Year of publication
2000
Pages
1042 - 1070
Database
ISI
SICI code
0042-1308(2000)69:11<1042:PCOCHC>2.0.ZU;2-0
Abstract
Characteristic features of the coordination chemistry of Cu(I) and the mech anisms of catalytic transformations of alkynes in the CuCl-MCl-H2O-HC=CR sy stem (MCl are alkali metal and ammonium chloride and amine hydrochlorides; R is H, CH2OH, CH = CH2, etc.) are analysed resorting to studies of the com positions and structure of copper(I) chloride(bromide) complexes, alkyne pi -complexes and ethynyl organometallic polynuclear compounds formed in this system in solutions and in the crystalline state. The role of polynuclear complexes in various reactions of alkynes is discussed.