The absorption spectra of poly(methyl methacrylate) (PMMA) doped with the p
hotoinitiator 2,2-dimethoxy 2-phenylacetophenone (DMPA) change under illumi
nation with UV light. Time-resolved measurements of the kinetics of the abs
orption changes at 352 nm prove the existence of a second light-induced rea
ction besides the expected light-induced decay of the photoinitiator. We pr
opose a model for this second process which is in good agreement with the o
bserved experimental facts.