Rh. Cheng et al., Potential phase control of chromium oxide thin films prepared by laser-initiated organometallic chemical vapor deposition, APPL PHYS L, 78(4), 2001, pp. 521-523
We have used laser-initiated chemical vapor deposition to grow the chromium
oxide thin films through the oxidation of Cr(CO)(6) in an oxygen environme
nt. While both Cr2O3 and CrO2 are present in the film, the relative weight
of each phase depends on the oxygen partial pressure. The Curie temperature
of the film increases and approaches the bulk T-C of CrO2 (397 K) as the p
artial oxygen pressure is increased. (C) 2001 American Institute of Physics
.