Electronic effects in the thermal C-2-C-6 biradical cyclisation of enyne-allenes

Citation
M. Schmittel et M. Maywald, Electronic effects in the thermal C-2-C-6 biradical cyclisation of enyne-allenes, CHEM COMMUN, (2), 2001, pp. 155-156
Citations number
36
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
2
Year of publication
2001
Pages
155 - 156
Database
ISI
SICI code
1359-7345(2001):2<155:EEITTC>2.0.ZU;2-O
Abstract
A comprehensive study on the influence of substituents at the alkyne termin us on the thermal biradical cyclisation of enyne-allenes shows a good agree ment of the rates with sigma (+).