A tetraazaporphyrin with an intense, broad near-IR band

Authors
Nemykin, VN Kobayashi, N
Citation
Vn. Nemykin et N. Kobayashi, A tetraazaporphyrin with an intense, broad near-IR band, CHEM COMMUN, (2), 2001, pp. 165-166
Citations number
22
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
2
Year of publication
2001
Pages
165 - 166
Database
ISI
SICI code
1359-7345(2001):2<165:ATWAIB>2.0.ZU;2-0
Abstract
A tetraazaporphyrin (TAP) prepared by condensation of 1-ferrocenyl-1,2,2-tr icyanoethylene in the presence of magnesium shows an intense, broad near-IR band in the 700-1300 nm region, which may be ascribed to charge-transfer t ransitions from the ferrocenyl moiety (substituents) to the TAP ligand.