Transport properties of anion exchange membranes in contact with organic ions. Part II. Influence of the size of the aromatic chain

Citation
R. Delimi et al., Transport properties of anion exchange membranes in contact with organic ions. Part II. Influence of the size of the aromatic chain, CR AC S IIC, 3(11-12), 2000, pp. 861-866
Citations number
7
Categorie Soggetti
Chemistry
Journal title
COMPTES RENDUS DE L ACADEMIE DES SCIENCES SERIE II FASCICULE C-CHIMIE
ISSN journal
13871609 → ACNP
Volume
3
Issue
11-12
Year of publication
2000
Pages
861 - 866
Database
ISI
SICI code
1387-1609(200011/12)3:11-12<861:TPOAEM>2.0.ZU;2-K
Abstract
The physico-chemical properties of an anion exchange membrane (ADS, Solvay) were studied in aqueous solutions containing both a mineral salt (10(-1) M NaCl) and an organic salt (10(-2) to 10(-1) M). The organic salt was a sod ium carboxylate or sulfonate bearing one or two aromatic rings. Measurement s of ion exchange, water content, electric resistance, self-diffusion and e lectrodiffusion fluxes were performed. According to the concentration, the organic anions with highly hydrophobic character can induce a poisoning of the membrane. (C) 2000 Editions scientifiques et medicales Elsevier SAS.